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What version of the Arduino IDE are you using? From your screenshot, it looks like you might be using one of the newer versions. On our software instructions page here: https://www.envirodiy.org/mayfly/software/ we recommend that you use the Legacy v1.8.x version since there are some quirks about the newer v2.0 and web-based Arduino IDE’s that can cause issues with the Mayfly.
When you plug your CP2102 Friend into your computer’s USB port, what does Windows Device Manager say? Does a “Silicon Labs CP210x USB to UART Bridge (COMx)” show up under the “Ports (COM & LPT)” list, or is it shown under an Unknown Device tab with a yellow triangle?